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No Previous knowledge of polymers is assumed in this book which provides a general introduction to the physics of solid polymers.

The book covers a wide range of topics within the field of polymer physics,beginning with a brief histor of hte developmert of synthetic polymers and an overview of the methods of polymerisation and processing .In the following chapter,David Bower describes important experimenttal techniques used in the study of polymers.The main part of the book,however,is deoted to the structure and properties of solid polymers,including blends,copolymers and liquid-crystal polymers,

With an approach appropricate for advanced undergraduate and graduate students of physics,materials science and chemistry,the book includes many worked examples and problems with solutions It will provide a firm firm foundation for the study of the physics of solid polymers.

作者简介：

DAVID BOWER received his D.Phil.from the University of Oxford in 1964.In 1990 he became a reader in the Department of Physics at the Universiyt of Leeds,retiring from this position in 1995.He was a founder member of the management committee of the IRC in Polymer Science and Technology(Universities of Leeds,Durham and Bradford),and co-authored The Vibrational Spectrosopy of Polymers with W.F.Maddams(CUP,1989).His contribution to the primary literature has included work on polymers,solid-state physics and magnetism.

Preface

Acknowledgements

1 Introduction

1.1 Polymers and the scope of the book

1.2 A brief history of the development of synthetic polymers

1.3 The chemical nartue of polymers

1.4 Properties and applications

1.5 Polymer processing

1.6 Further reading

2 Some physical tecniques for studying polymers

2.1 Introduction

2.2 Differential scanning calorimetry (DSC)and differential thermal analysis(DTA)

2.3 Density measurement

2.4 Light scattering

2.5 X-ray scattering

2.6 Infrared and Raman spectroscopy

2.7 Nuclear magnetic resonanec spetroscopy(NMR)

2.8 Optical and electron microscopy

2.9 Further reading

3 Molecular sizes and shapes and ordered structures

3.1 Introduction

3.2 Distributions of molar mass and their determination

3.3 The shapes of polymer molecules

3.4 Evidence for ordered structures in solid polymers

3.5 Further reading

3.6 Problems

4 Regular chaing and crystallinity

4.1 Regular and irregular chains

4.2 The determination of crystal structures by X-ray diffraction

4.3 Information about crystal structures from other methods

4.4 Crystal structures of some common polymers

4.5 Further reading

4.6 Problems

5 Morphology and motion

5.1 Introduction

5.2 The degree of crystallinity

5.3 Crystallites

5.4 Non-crystalline regions and polymer macro-comformations

5.5 Spherulites and other polycrstalline structures

5.6 Crystallisation and melting

5.7 Molecular motion

5.8 Further reading

5.9 Problems

6 Mechanical properties I-time-independent elasticity

6.1 Introduction to the mechanical properties of polymers

6.2 Elastic properties of isotropic polymers at small strains

6.3 The phenomenology of rubber elasticity

6.4 The statistical theory of rubber elasticity

6.5 Modifications of the simple molecular and phenomenological theories

6.6 Further reading

6.7 Problems

7 Mechanical properties II-linear viscoelasticity

7.1 Introduction and definitions

7.2 Mechanical models

7.3 Experimental methods for studyingviscoelastic behaviour

7.4 Time-temperature equivalence and superposition

7.5 The glass transition in amorphous polymers

7.6 Relaxations for amorphous and crystalline polymers

7.7 Further reading

7.8 Problems

8 Yield and fracture of polymers

8.1 Introduction

8.2 Yield

8.3 Fracture

8.4 Further reading

8.5 Problems

9 Electrical and optical properties

9.1 Introduction

9.2 Electrical Polarisation

9.3 Conducting polymers

9.4 Optical properties of polymers

9.5 Further reading

9.6 Further reading

10 Oriented polymers I-production and characterisation

10.1 Introductin-hte meaning and importance of orientation

10.2 The productin of orientation in synthetic polymers

10.3 The mathematical description of molecular orientation

10.4 Methods of representingtypes of orientation

10.5 The combination of methods for two-phase systems

10.6 Methods of representing types of orientatin

10.7 Further reading

10.8 Problems

11 Oriented polymers II-models and properties

11.1 Introduction

11.2 Models for molecular orientation

11.3 Comparison between theory and experiment

11.4 Comparison between predicted and observed elastic properties

11.5 Takayanagi composite models

11.6 Highly oriented polymers nad ultimate moduli

11.7 Further reading

11.8 Problems

12 Polymer blends,copolymers and liquid-crystal polymers

12.1 Introduction

12.2 Polymer blends

12.3 Copolymers

12.4 Liquid-crystal polymers

12.5 Further reading

12.6 Problems

Appendix:cartesian tensors

Solutions to problems

Index

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