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《高分子化学原理》一书成书较早，作者是高分子界享有盛名的1974年度诺贝尔化学奖获得者P. J. 弗洛里。经过长达半个多世纪的考验，该书已经成为公认的高分子化学经典教科书，培养了几代高分子科学家。本书系高校化学及相关专业高分子科学入门教材，尽管未包括聚合物力学性质和高分子动力学或动态性质等方面的内容，但对聚合反应及反应动力学以及高分子溶液性质等均有系统讨论。

Preface

CHAPTER Ⅰ HISTORICAL INTRODUCTl0N

　1.Early Investigations on NaturaUy Occurring Polymers

　2.Early Encounters with Condensation Polymers

　3.Vinyl Polymers

　4.Rise of the Macromoleoular Hypothesis

References.

CHAPTER Ⅱ TYPES 0F POLYMERIC SUBSTANCES：DEFINITIONS AND CLASSIFICATIONS

　1.Primary Definitions

　2.Classification of Polymers

　3.Condensation Polymers and Condensation Polymerization

　4.Addition Pobrmers from Unsaturated Monomers

　5.Polymerization of Cyclic Compounds

　6.Anomalous Conden8ation Polymerizations

　7.Inorganic Polymers

　8.Concluding Remarks on the Structure and Properties of High Polymers

References.

CHAPTER Ⅲ MOLECULAR SIZE AND CHEMICAL REACTIVITY；PRINCIPLES OF CONDENSATION POLYMERIZATION

　1.Chemical Reactivity in Homologous Series of Monomeric Com—pouuds

2.Theory of the Reactivity of Large Molecules

3.Kinetics of Condensation Polymerization

4.Kinetics of Degradation of Condensation Polymers

　　4a.Hydrolysis of Cellulose and Cellulose Derivatives

4b.Hydrolysis of Polyamides

　 4c.Alcoholysis of Polyesters

4d.Interchange Reactions in Condensation Polymers

5.Molecular Weights of Linear Condensation Polymers

6.Ring Formation vs.Chain Polymerization

7.Summary and Conclusions: The Principle of Equal Reactivity of All Functional Groups

References.

CHAPTER Ⅳ POLYMERIZATION OF UNSATURATED MONOMERS BY FREE RADICAL MECHANISMS

　1.The Conversion of Monomer to Polymer

　　1a.Kinetic Scheme for Polymerization in the Presence of an Initiator

1b.Dependence of Initial Rates on the Concentrations of Initi-ator and Monomer

1c.Initiator Efficiencies

1d.Evaluation of Parameters

1e.The Course of the Conversion of Monomer to Polymer;Autoacceleration

1f.Kinetics of Thermal Polymerization

　2.Chain Lengths

2a.Kinetic Chain Length and Degree of Polymerization

2b.Kinetics of Chain Transfer.

2c.Chain Transfer in Undiluted Monomer; Evaluation of Parameters

2d.Chain Transfer with Solvents

2e.Dependence of the Degree of Polymerization on Tempera-ture

2f.Regulators

　3.Absolute Values of the Rate Constants for Individual Steps

3a.Methods for Determining the Mean Lifetime of an Active Center.

3b.Experimental Results

　4.Inhibition and Retardation of Polymerization

4a.Reaction Mechanisms

4b.Kinetics of Inhibition and Retardation

4c.Allylic Polymerization; Autoinhibition

References.

CHAPTER Ⅴ COPOLYMERIZATION,EMULSION POLYMERIZATION AND IONIC POLYMERIZATION

CHAPTER Ⅵ THE STRUCTURE OF VINYL POLYMERS

CHAPTER Ⅶ DETERMINATION OF MOLECULAR WEIGHTS

CHAPTER Ⅷ MOLECULAR WEIGHT DISTRIBUTIONS IN LINEAR POLYMERS

CHAPTER Ⅸ MOLECULAR WEIGHT DISTRIBUTIONS IN NONLINEAR

CHAPTER Ⅹ CONFIGTURATION OF POLYMER CHAINS

CHAPTER Ⅺ RUBBER ELASTICITY

CHAPTER Ⅻ STATISTICAL THERMODYNAMICS OF POLYMER SOLUTIONS

CHAPTER XIII PHASE EQUILIBRIA IN POLYMER SYSTEMS

CHAPTER XIV CONFIGURATIONAL AND FRICTIONAL PROPERTIES OF THE POLYMER MOLECULE IN DILUTE SOLUTION

GLOSSARY OF PRINCIPAL SYMBOLS

AUTHOR INDEX

SUBJECT INDEX

Paul J. Flory，1974年度诺贝尔化学奖得主，实验家和理论家，高分子科学理论的主要开拓者和奠基人之一。由于作者在“大分子物理化学实验和理论两方面做出了根本性的贡献”而荣获1974年度诺贝尔化学奖。

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书籍介绍

《高分子化学原理》一书成书较早，作者是高分子界享有盛名的1974年度诺贝尔化学奖获得者P. J. 弗洛里。经过长达半个多世纪的考验，该书已经成为公认的高分子化学经典教科书，培养了几代高分子科学家。本书系高校化学及相关专业高分子科学入门教材，尽管未包括聚合物力学性质和高分子动力学或动态性质等方面的内容，但对聚合反应及反应动力学以及高分子溶液性质等均有系统讨论。